Hello --
It's an odd symptom, but sometimes happens when one's heart starts beating in a regularly irregular fashion called ventricular bigemeny. It's not really serious, just a regular occurence of a premature heartbeat followed by a normal one. This can, if timed a certain way, cause
pain or pressure. This sort of
arrhythmia is often seen in association with short-term steroid use, too. Heart
pain also often occurs when lying down if the patient has pericarditis, an inflammation of the sac around the heart, which also may have some fluid buildup inside it. This is possible since your mother recently an angiogram, which can sometimes cause this sort of inflammation. Other than these two things it's hard to imagine what could be causing
pain in time with the heart beat, that is, if I am understanding the description right. If she simply has
pain when she's sitting or lying down then pericarditis is more likely. Of course there are other, more obscure possible causes, such as sliding hiatal hernia, but this probably would have been present for a long time before now.
All the above mentioned things are pretty benign. If the problem persists or becomes more pronounced then it most certainly should be checked, but if it remains stable and only happens in relation to posture, it's probably nothing very serious.
I hope this is helpful. If you have any further information, by all means share it or just follow up with us as needed. Good luck to you and your mother.